Free vs Bound Charge

D  = ε0 E  +  P

Free charges sit on the plates. If a dielectric is present, it polarizes and creates bound surface charge. Set susceptibility to zero to remove the material and return to vacuum.

Free surface charge σf 50
Susceptibility χe 2.0
free charge on plates
bound charge on dielectric
D: free charge only
E: total field
P: polarization